As well as the four-day Spanish session, the team confirmed they will also attend the other two pre-season tests in Bahrain, the first of which runs from February 19-22 and the second from February 27 - March 2.
Caterham, who are yet to announce their 2014 driver line-up, are the third team after McLaren and Mercedes to officially confirm their attendance at the Jerez test with their new car.
Lotus revealed on Monday that they will not attend the Spanish session and will instead debut their new machine, the E22, at the first of the Bahrain tests.